Tetraalkynyl calix[4]arenes with advanced NLO properties

Rigid, highly conjugated tetraalkynyl-calix[4]arenes synthesised via Sonogashira coupling give rise to improved second-order hyperpolarizability values as determined by hyper-Rayleigh scattering-a technique that in addition to X-ray crystallography also allows for the conformational analysis of the calixarene structures in solution.

Tetraalkynyl calix[4]arenes with advanced NLO properties

G. Hennrich, M. T. Murillo, P. Prados, K. Song, I. Asselberghs, K. Clays, A. Persoons, J. Benet-Buchholz, J. de Mendoza

Chem. Commun. 2005, 2747-2749
DOI: Go to the journal

Associated ICIQ research group/s:

  • RESEARCH GROUP/S
    Emeritus Prof. Javier de Mendoza
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