A Redox-Active C3-Symmetric Triindole-Based Triazacyclophane

The highly stable dimeric radical cation of a C3-symmetric triazacyclophane (see picture), with the positive charge delocalized over the two molecules, offers an excellent model for the study of intermolecular communication depending on hole hopping.

Redox-active C3-symmetric triindole based triazacyclophane

B. Gómez-Lor, G. Hennrich, B. Alonso, A. Monge, E. Gutierrez-Puebla, A. M. Echavarren

Angew. Chem. Int. Ed. 2006, 45, 4491-4494
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