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Porphyrin-silver acetylide cluster catalysts with dual active sites for the electrochemical reduction of CO2

A one-step synthesis of porphyrin-silver acetylide clusters from tetra alkyne-substituted porphyrin is described. The solid-state properties of three 2D-like compounds were fully characterised using XPS and XRD while their catalytic properties under CO2 electroreduction reaction conditions were assessed and their faradaic efficiency quantified.

Curet, L.; Foix, D.; Palomares, E.; Billon, L.; Viterisi, A.

Chem. Commun. 2024
DOI: 10.1039/d4cc03836c

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