New dinuclear iodine(III) reagents for the intermolecular diamination of alkenes are reported. These are accessible through protolytic aminolysis events, which generate defined imido-iodine(III) groups.
![Oxidative diamination promoted by dinuclear iodine(III) reagents](https://www.iciq.org/wp-content/uploads/2014/03/Oxidative-diamination_1008.gif)
New dinuclear iodine(III) reagents for the intermolecular diamination of alkenes are reported. These are accessible through protolytic aminolysis events, which generate defined imido-iodine(III) groups.