Homogeneous palladium catalysis enables a novel intermolecular regioselective diamination of allylic ethers, which offers a convenient entry into 1,2,3-trisubstituted products. These represent suitable building blocks with differently protected nitrogen atoms for subsequent synthetic application.
![Intermolecular regioselective 1,2-diamination of allylic ethers](https://www.iciq.org/wp-content/uploads/2014/03/Intermolecular-regioselective_689.gif)