Formal (4+1) Cycloaddition of Methylenecyclopropanes with 7-Aryl-1,3,5-cycloheptatrienes by Triple Gold(I) Catalysis

7-Aryl-1,3,5-cycloheptatrienes react intermolecularly with methylenecyclopropanes in a triple gold(I)-catalyzed reaction to form cyclopentenes. The same formal (4+1) cycloaddition occurs with cyclobutenes. Other precursors of gold(I) carbenes can also be used as the C1 component of the cycloaddition.

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Y. Wang, M. E. Muratore, Z. Rong, A. M. Echavarren

Angew. Chem. Int. Ed. 2014, 53, 14022-14026
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Associated ICIQ research group/s:

  • RESEARCH GROUP/S
    Prof. Antonio M. Echavarren
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