7-Aryl-1,3,5-cycloheptatrienes react intermolecularly with methylenecyclopropanes in a triple gold(I)-catalyzed reaction to form cyclopentenes. The same formal (4+1) cycloaddition occurs with cyclobutenes. Other precursors of gold(I) carbenes can also be used as the C1 component of the cycloaddition.
Y. Wang, M. E. Muratore, Z. Rong, A. M. Echavarren
Angew. Chem. Int. Ed. 2014, 53, 14022-14026
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