Consent Preferences
Customize Consent Preferences

We use cookies to help you navigate efficiently and perform certain functions. You will find detailed information about all cookies under each consent category below.

The cookies that are categorized as "Necessary" are stored on your browser as they are essential for enabling the basic functionalities of the site. ... 

Always Active

Necessary cookies are required to enable the basic features of this site, such as providing secure log-in or adjusting your consent preferences. These cookies do not store any personally identifiable data.

Functional cookies help perform certain functionalities like sharing the content of the website on social media platforms, collecting feedback, and other third-party features.

Analytical cookies are used to understand how visitors interact with the website. These cookies help provide information on metrics such as the number of visitors, bounce rate, traffic source, etc.

Performance cookies are used to understand and analyze the key performance indexes of the website which helps in delivering a better user experience for the visitors.

No cookies to display.

Advertisement cookies are used to provide visitors with customized advertisements based on the pages you visited previously and to analyze the effectiveness of the ad campaigns.

No cookies to display.

Other cookies are those that are being identified and have not been classified into any category as yet.

No cookies to display.

Electrochemical promotion of a dispersed Ni catalyst for H2 production via partial oxidation of methanol

This study reports the electrochemical promotion (EPOC) of Ni particles dispersed in a diamond-like carbon (DLC) matrix. A Ni-DLC (Ni/C molar ratio of 0.1) catalyst film was prepared on a K-βAl2O3 (K+-conductor) solid electrolyte by cathodic arc deposition (CAD). This physical vapour deposition (PVD) technique allows to decrease the metal loading used in the solid electrolyte cell and to electrochemically activate dispersed Ni particles in the methanol partial oxidation (POM) reaction by in-situ controlling the coverage of K+ ions electrochemically transferred to the catalyst surface. As compared with a pure Ni layer prepared by the same technique, the Ni-DLC catalyst film shows a higher specific activity and an improved oxidation resistance under EPOC working reaction conditions. The possibility of electrochemically activate (with a negligible energy consumption) dispersed particles of a non-noble metal catalyst (closely related to commercially catalyst formulations) is of great interest for a further commercialization step of the EPOC phenomena in H2 production reactions and in other catalytic systems.

Random publication image

J. González-Cobos, E. Ruiz-López, J.L. Valverde and A. de Lucas-Consuegra

International Journal of Hydrogen Energy 2016, 19418-19429. DOI: 10.1016/j.ijhydene.2016.06.027
DOI: Go to the journal

Associated ICIQ research group/s:

Go to the journal
  • SHARE

Let's create a brighter future

Join our team to work with renowned researchers, tackle groundbreaking
projects and contribute to meaningful scientific advancements

Join us!
Board of Trustees:
Member of:
Accredited with:
With the support of: