Phosphinoimidazoline (PHIM) ligands bearing a triazolylmethyl substituent at the sp3 nitrogen atom in the imidazoline ring lead to highly improved enantioselectivity (up to 99% ee) in allylic substitution reactions with respect to analogous ligands with substituents lacking the triazole unit. NMR and theoretical studies support a shift in the coordination mode of the PHIM ligand to palladium, triggered by a very favourable interaction with the triazole unit.
![Changing the palladium coordination to phosphinoimidazolines with a remote triazole substituent](https://www.iciq.org/wp-content/uploads/2014/03/Changing-the-palladium_3255.gif)