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Intranet

Room-Temperature-Stable Magnesium Electride via Ni(II) Reduction

Herein, we report the synthesis of highly reduced bipyridyl magnesium complexes and the first example of a stable organic magnesium electride supported by quantum mechanical computations and X-ray diffraction. These complexes serve as unconventional homogeneous reductants due to their high solubility, modular redox potentials, and formation of insoluble, non-coordinating byproducts. The applicability of these reductants is showcased by accessing low-valent (bipy)2Ni(0) species that are challenging to access otherwise.

Day, C. S.; Dat Do, C.; Odena, C.; Benet-Buchholz, J.; Xu, L., Foroutan-Nejad, C.; Hopmann, K. H.; Martin, R.

J. Am. Chem. Soc. 2022, 144 (29), 13109–13117
DOI: 10.1021/jacs.2c01807

Open access

Associated ICIQ research group/s:

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