New vistas in transmetalation with discrete “AgCF₃” species: Implications in Pd‐mediated trifluoromethylation reactions

This work describes the employment of discrete “AgCF₃” complexes, including unique (Cat)[Ag(CF₃)₂] salts, as efficient transmetalating agents to PdII in order to tackle some of the usually overshadowed limitations related to this step within the trifluoromethylation area.