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Intranet

Pauson-Khand reaction of amino acid derived 3-pyrrolines: New enantiopure scaffolds for diversity-oriented synthesis

Amino acid derived 3-pyrrolines can be readily prepared in a single step in enantiomerically pure form by cycloalkylation of the corresponding amino esters with (Z)-1,4-dichloro-2-butene. Enantiopure azabicyclo[3.3.0]octenones can be then easily obtained through an unprecedented Pauson-Khand reaction followed by diastereomer separation.

Pauson-Khand reaction of amino acid derived 3-pyrrolines: New enantiopure scaffolds for diversity-oriented synthesis

F. Cuevas, C. García-Granda, H. Buschmann, A. Torrens, S. Yenes, M. A. Pericàs

Synlett 2007, 119-122

Associated ICIQ research group/s:

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