We here report the synthesis of bifunctional catalysts that can be assembled using simple, cheap and accessible building blocks based on resorcinarenes, and their application as efficient, one-component homogeneous catalysts in the coupling of both terminal and internal epoxides with carbon dioxide affording their cyclic carbonate products. Furthermore, a heterogeneous version was also prepared that combines the activity of these bifunctional systems with excellent stability and recycling potential, allowing for a turnover of >1250. This newly prepared organocatalyst obviates the use of any metal, solvent or additives marking it as an attractive catalyst for CO2 valorization