The combination of the square-planar cis-protected [Pt(dppp)(O₃SCF₃)₂] (M) with the ditopic N,N′-bis(3,5-dimethyl-4-pyridinyl)-4-ethoxy-2,6-pyridinedicarboxamide ligand (L) leads both in solution and in the solid state to the quantitative self-assembly of a M₂L₂ metallocycle. We also report crystallographic evidence derived from the solid-state structure of the dinuclear metallocycle in support of the existence of anion-π-π interactions.