General route is presented toward the template-directed preparation of self-assembled heteromultimetallic salen structures using noncovalent coordinative metal-ligand interactions. Various higher order assemblies have been studied in detail using a combination of NMR spectroscopy and X-ray crystallography.
S. J. Wezenberg, E. C. Escudero-Adán, J. Benet-Buchholz, A. W. Kleij
Inorg. Chem. 2008, 47, 2925-2927
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