Ruthenium-catalyzed nucleophilic fluorination of halobenzenes
The first π-coordination-catalyzed nucleophilic fluorination of unactivated aryl halides has been demonstrated. Chlorobenzene reacts with alkali metal fluorides (CsF, KF) in the presence of a Cp*Ru catalyst at 120–180 °C to give fluorobenzene.
A. I. Konovalov, E. O. Gorbacheva, F. M. Miloserdov, V. V. Grushin
Chem. Commun. 2015, 51, 13527-13530
DOI:
Go to the journal
- SHARE
Let's create a brighter future
Join our team to work with renowned researchers, tackle groundbreaking
projects and contribute to meaningful scientific advancements
