A multipurpose gold(I) precatalyst
[Au(tmbn)2](SbF6) is the first gold(I) complex supported by two nitrile ligands that is indefinitely stable at room temperature. This is a highly versatile precatalyst that can be used for the preparation of active and robust solid-supported gold(I) catalysts.
M. Raducan, C. Rodríguez-Escrich, X. C. Cambeiro, E. C. Escudero-Adán, M. A. Pericàs, A. M. Echavarren
Chem. Commun. 2011, 47, 4893-4895
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