1,2-Arylsulfonylation of Vinyl Ethers and Esters Enabled by Dual Ni Catalysis

A dual photocatalytic sulfonylation-arylation of electron-rich alkenes is described. By combining sulfinate salts, (hetero)-aryl-bromides and 2,3-dihydrofuran under Ru and Ni dual catalysis, over 35 examples of aryl-sulfonylated scaffolds could be obtained in good to excellent yields, under mild reaction conditions and high diastereoselectivity.

Pugnal, L. V. B. L.; Vega, K. B.; Pissinati, E. F.; Correia, J. T. M.; Zukerman-Schpector, J., Martin, R.; Paixão, M. W

ChemCatChem 2023
DOI: 10.1002/cctc.202201434

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